Coordination Polymerization of Renewable 3-Methylenecyclopentene with Rare-Earth-Metal Precursors
 
作者:Bo Liu, Shihui Li, Meiyan Wang, Dongmei Cui,
关键字:3-methylenecyclopentene,coordination polymerization,rare-earth metals,renewable resources,terpenes
论文来源:期刊
具体来源:http://onlinelibrary.wiley.com/doi/10.1002/anie.201700546/full
发表时间:2017年


Polyamorous catalysis: Rare-earth-metal precursors supported by moderately bulky ligands mediated polymerization of renewable 3-methylenecyclopentene (MCP) monomers. The rare-earth-metal catalysts were highly active and yielded regiopure 1,4-poly(MCP) with targeted molecular weights across a wide range of polymerization temperatures.