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Living catalyzed-chain-growth polymerization and block copolymerization of isoprene by rare-earth metal allyl precursors bearing a constrained-geometry-conformation ligandw

作者:Zhongbao Jian, Dongmei Cui, Zhaomin Hou and Xiaofang Li
关键字:aminophenyl functionalized cyclopentadienyl ligated,cis-1,4 selectivity, living reversible, chain transfer, aluminium additives
论文来源:期刊
具体来源:http://pubs.rsc.org/en/content/articlepdf/2010/cc/b926813h
发表时间:2010年

Aminophenyl functionalized cyclopentadienyl ligated rare-earth metal allyl mediated cationic systems display high cis-1,4 selectivity for the polymerization of isoprene, and living reversible and rapid chain transfer to aluminium additives.